Effects of Methyl Substitution in Ruthenium Tris(2-pyridylmethyl)amine Photocaging Groups for Nitriles

Four complexes of the general formula [Ru(L)(CH(3)CN)(2)](PF(6))(2), [L = TPA (5), MeTPA (6), Me(2)TPA (7), and Me(3)TPA (8)] [TPA = tris[(pyridin-2-yl)methyl]amine, where methyl groups were introduced consecutively onto the 6-position of py donors of TPA, were prepared and characterized by various...

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Veröffentlicht in:Inorg Chem
Hauptverfasser: Arora, Karan, White, Jessica K., Sharma, Rajgopal, Mazumder, Shivnath, Martin, Philip D., Schlegel, H. Bernhard, Turro, Claudia, Kodanko, Jeremy J.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2016
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4966558/
https://ncbi.nlm.nih.gov/pubmed/27355786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b00650
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