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Selective Photodissociation of Acetonitrile Ligands in Ruthenium Polypyridyl Complexes Studied by Density Functional Theory

Metal complexes that release ligands upon photoexcitation are important tools for biological research and show great potential as highly specific therapeutics. Upon excitation with visible light, [Ru(TQA)(MeCN)(2)](2+) [TQA = tris(2-quinolinylmethyl)amine] exchanges one of the two acetonitriles (MeC...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Tu, Yi-Jung, Mazumder, Shivnath, Endicott, John F., Turro, Claudia, Kodanko, Jeremy J., Schlegel, H. Bernhard
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4743049/
https://ncbi.nlm.nih.gov/pubmed/26244447
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b01202
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