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Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF(2)H‐Containing Alcohols
We have developed a novel and simple protocol for the direct incorporation of a difluoromethyl (CF(2)H) group into alkenes by visible‐light‐driven photoredox catalysis. The use of fac‐[Ir(ppy)(3)] (ppy=2‐pyridylphenyl) photocatalyst and shelf‐stable Hu's reagent, N‐tosyl‐S‐difluoromethyl‐S‐phen...
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| Publié dans: | Chemistry |
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| Auteurs principaux: | , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
John Wiley and Sons Inc.
2015
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4737308/ https://ncbi.nlm.nih.gov/pubmed/26639021 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201504838 |
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