Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF(2)H‐Containing Alcohols

We have developed a novel and simple protocol for the direct incorporation of a difluoromethyl (CF(2)H) group into alkenes by visible‐light‐driven photoredox catalysis. The use of fac‐[Ir(ppy)(3)] (ppy=2‐pyridylphenyl) photocatalyst and shelf‐stable Hu's reagent, N‐tosyl‐S‐difluoromethyl‐S‐phen...

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Dades bibliogràfiques
Publicat a:Chemistry
Autors principals: Arai, Yusuke, Tomita, Ren, Ando, Gaku, Koike, Takashi, Akita, Munetaka
Format: Artigo
Idioma:Inglês
Publicat: John Wiley and Sons Inc. 2015
Matèries:
Communications
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4737308/
https://ncbi.nlm.nih.gov/pubmed/26639021
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201504838
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