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β-Selective Aroylation of Activated Alkenes by Photoredox Catalysis
Late-stage synthesis of α,β-unsaturated aryl ketones remains an unmet challenge in organic synthesis. Herein, we report a photocatalytic non-chain radical aroyl-chlorination of alkenes via 1,3-chlorine atom shift to form β-chloroketones as masked enones that liberate the desired enones upon workup....
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6527503/ https://ncbi.nlm.nih.gov/pubmed/30994977 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201901874 |
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