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Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis

Regioselective amino-difluoromethylation of aromatic alkenes via C(sp(3))–CF(2)H and C(sp(3))–N bond formation with the C[double bond, length as m-dash]C moiety has been achieved in a single operation by visible-light photoredox catalysis. The combination of a shelf-stable and easy-to-handle sulfoni...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Noto, Naoki, Koike, Takashi, Akita, Munetaka
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5628600/
https://ncbi.nlm.nih.gov/pubmed/28989669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01703k
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