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Spiro-fused carbohydrate oxazoline ligands: Synthesis and application as enantio-discrimination agents in asymmetric allylic alkylation

In the present work, we describe a convenient synthesis of spiro-fused D-fructo- and D-psico-configurated oxazoline ligands and their application in asymmetric catalysis. The ligands were synthesized from readily available 3,4,5-tri-O-benzyl-1,2-O-isopropylidene-β-D-fructopyranose and 3,4,5-tri-O-be...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Kraft, Jochen, Golkowski, Martin, Ziegler, Thomas
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4734355/
https://ncbi.nlm.nih.gov/pubmed/26877819
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.18
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