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The Composition and Structure of the Inorganic Core of Relaxed Intermediate X(Y122F) of E. coli Ribonucleotide Reductase

Activation of the diferrous center of the β(2) (R2) subunit of the class 1a Escherichia coli ribonucleotide reductases (RNR) by reaction with O(2) followed by one-electron reduction yields a spin-coupled, paramagnetic Fe(III)/Fe(IV) intermediate, denoted X, whose identity has been sought by multiple...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Doan, Peter E., Shanmugam, Muralidharan, Stubbe, JoAnne, Hoffman, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4732524/
https://ncbi.nlm.nih.gov/pubmed/26636616
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b10763
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