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Kinetics of radical intermediate formation and deoxynucleotide production in 3-aminotyrosine-substituted Escherichia coli ribonucleotide reductases

Escherichia coli ribonucleotide reductase is an α2β2 complex and catalyzes the conversion of nucleoside 5´-diphosphates (NDPs) to 2´-deoxynucleotides (dNDPs). The reaction is initiated by the transient oxidation of an active-site cysteine (C(439)) in α2 by a stable diferric tyrosyl radical (Y(122)•)...

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Main Authors: Minnihan, Ellen C., Seyedsayamdost, Mohammad R., Uhlin, Ulla, Stubbe, JoAnne
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2011
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3125130/
https://ncbi.nlm.nih.gov/pubmed/21612216
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201640n
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