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Dual catalytic decarboxylative allylations of α-amino acids and their divergent mechanisms
The room temperature radical decarboxylative allylation of N-protected α-amino acids and esters has been accomplished via a combination of palladium and photoredox catalysis to provide homoallylic amines. Mechanistic investigations revealed that the stability of the α-amino radical, which is formed...
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Publicado no: | Chemistry |
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Main Authors: | , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2015
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4715668/ https://ncbi.nlm.nih.gov/pubmed/26526115 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201503644 |
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