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Dual catalytic decarboxylative allylations of α-amino acids and their divergent mechanisms

The room temperature radical decarboxylative allylation of N-protected α-amino acids and esters has been accomplished via a combination of palladium and photoredox catalysis to provide homoallylic amines. Mechanistic investigations revealed that the stability of the α-amino radical, which is formed...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chemistry
Prif Awduron: Lang, Simon B., O’Nele, Kathryn M., Douglas, Justin T., Tunge, Jon A.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2015
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC4715668/
https://ncbi.nlm.nih.gov/pubmed/26526115
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201503644
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