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Mechanistic origin of the stereodivergence in decarboxylative allylation

[Image: see text] A stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe suggests that the mechanism of DcA reactions can change based on the substitution pattern at the α-carbon of the nucleophile, however reaction via stabilized malonate nucleophiles i...

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Detalhes bibliográficos
Main Authors: Chattopadhyay, Kalicharan, Jana, Ranjan, Day, Victor W., Douglas, Justin T., Tunge, Jon A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2913676/
https://ncbi.nlm.nih.gov/pubmed/20533852
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101042x
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