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Mechanistic origin of the stereodivergence in decarboxylative allylation
[Image: see text] A stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe suggests that the mechanism of DcA reactions can change based on the substitution pattern at the α-carbon of the nucleophile, however reaction via stabilized malonate nucleophiles i...
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| Hauptverfasser: | , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2913676/ https://ncbi.nlm.nih.gov/pubmed/20533852 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol101042x |
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