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Structural Examination of the Transient 3-Aminotyrosyl Radical on the PCET Pathway of E. coli Ribonucleotide Reductase by Multifrequency EPR Spectroscopy
[Image: see text] E. coli ribonucleotide reductase (RNR) catalyzes the conversion of nucleotides to deoxynucleotides, a process that requires long-range radical transfer over 35 Å from a tyrosyl radical (Y(122)•) within the β2 subunit to a cysteine residue (C(439)) within the α2 subunit. The radical...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2009
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4703294/ https://ncbi.nlm.nih.gov/pubmed/19821570 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja903879w |
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