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Synthesis of 2,5-Diaryl-1,5-Dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis
Visible-light photoreductive coupling of 2-arylallyl bromides in the presence of the photocatalyst Ru(bpy)(3)(PF(6))(2), a Hantzsch ester, and i-Pr(2)NEt gives 2,5-diaryl-1,5-dienes in high yield. This method avoids the use of stoichiometric metal reductants and is compatible with the presence of ha...
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| 出版年: | J Org Chem |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4697828/ https://ncbi.nlm.nih.gov/pubmed/26514061 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01962 |
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