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Synthesis of (±)-Tetrabenazine by Visible Light Photoredox Catalysis
(±)-Tetrabenazine was synthesized in six steps from commercially available compounds. The key cyclization substrate was assembled rapidly via Baylis-Hillman and aza-Michael reactions. Annulation of the final ring was achieved through visible light photocatalysis, wherein carbon-carbon bond formation...
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| Udgivet i: | J Org Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4684717/ https://ncbi.nlm.nih.gov/pubmed/26544155 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b02199 |
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