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Electrocatalytic O(2)-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a “Bridging Peroxo” Intermediate Involved in Facile 4e(−)/4H(+) O(2)-Reduction
[Image: see text] A synthetic heme–Cu CcO model complex shows selective and highly efficient electrocatalytic 4e(−)/4H(+) O(2)-reduction to H(2)O with a large catalytic rate (>10(5) M(−1) s(−1)). While the heme-Cu model (FeCu) shows almost exclusive 4e(−)/4H(+) reduction of O(2) to H(2)O (detecte...
Αποθηκεύτηκε σε:
| Τόπος έκδοσης: | J Am Chem Soc |
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| Κύριοι συγγραφείς: | , , , , |
| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2015
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4690469/ https://ncbi.nlm.nih.gov/pubmed/26419806 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06513 |
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