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Direct observation of intermediates formed during steady-state electrocatalytic O(2) reduction by iron porphyrins

Heme/porphyrin-based electrocatalysts (both synthetic and natural) have been known to catalyze electrochemical O(2), H(+), and CO(2) reduction for more than five decades. So far, no direct spectroscopic investigations of intermediates formed on the electrodes during these processes have been reporte...

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Bibliographic Details
Main Authors: Sengupta, Kushal, Chatterjee, Sudipta, Samanta, Subhra, Dey, Abhishek
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3666701/
https://ncbi.nlm.nih.gov/pubmed/23650367
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1300808110
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