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Copper-catalyzed stereoselective conjugate addition of alkylboranes to alkynoates
A copper-catalyzed conjugate addition of alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) to alkynoates to form β-disubstituted acrylates is reported. The addition occurred in a formal syn-hydroalkylation mode. The syn stereoselectivity was excellent regardless o...
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| 出版年: | Beilstein J Org Chem |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Beilstein-Institut
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4685882/ https://ncbi.nlm.nih.gov/pubmed/26734092 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.11.265 |
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