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Synthesis of ent-Ketorfanol via a C–H Alkenylation/Highly Torquoselective 6π-Electrocyclization Cascade
The asymmetric synthesis of ent-ketorfanol from simple and commercially available precursors is reported. A Rh(I)-catalyzed intramolecular C–H alkenylation/highly torquoselective 6π-electrocyclization cascade provides a fused bicyclic 1,2-dihydropyridine as a key intermediate. Computational studies...
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| 發表在: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2015
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4676713/ https://ncbi.nlm.nih.gov/pubmed/26385263 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505604 |
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