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Origins of 1,6-Stereoinduction in Torquoselective 6π Electrocyclizations
A novel stereoselective electrocyclization developed for the total synthesis of reserpine has been explored by both experiment and theory. A stereocenter 6 atoms away from the newly forming chiral center is responsible for the diastereoselectivity of the ring closure. This stereogenic center – lying...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3632451/ https://ncbi.nlm.nih.gov/pubmed/23448287 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja400882y |
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