Electrochemical evidence that pyranopterin redox chemistry controls the catalysis of YedY, a mononuclear Mo enzyme

A long-standing contradiction in the field of mononuclear Mo enzyme research is that small-molecule chemistry on active-site mimic compounds predicts ligand participation in the electron transfer reactions, but biochemical measurements only suggest metal-centered catalytic electron transfer. With th...

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Detalles Bibliográficos
Publicado en:Proc Natl Acad Sci U S A
Autores principales: Adamson, Hope, Simonov, Alexandr N., Kierzek, Michelina, Rothery, Richard A., Weiner, Joel H., Bond, Alan M., Parkin, Alison
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2015
Materias:
Physical Sciences
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4664312/
https://ncbi.nlm.nih.gov/pubmed/26561582
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1516869112
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