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Allylic Selenosulfide Rearrangement: A Method for Chemical Ligation to Cysteine and Other Thiols
Alkylation of potassium selenosulfate with allylic halides gives Se-allyl seleno Bunte salts. On reaction with thiols at room temperature these afford mixed dialkyl selenosulfides, which undergo 2,3-sigmatropic rearrangement with loss of selenium, either spontaneously or with assistance by triphenyl...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4658652/ https://ncbi.nlm.nih.gov/pubmed/16492032 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja057521c |
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