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Silver-Mediated Allylic Disulfide Rearrangement for Conjugation of Thiols in Protic Media

[Image: see text] Alkyl and aryl allyl disulfides are induced to undergo the desulfurative allylic rearrangement by silver nitrate in protic solvents at room temperature, thereby removing the necessity for the use of phosphines as thiophilic reagents. The silver-mediated reaction functions at ambien...

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Autors principals: Crich, David, Subramanian, Venkataraman, Karatholuvhu, Maheswaran
Format: Artigo
Idioma:Inglês
Publicat: 2009
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2852026/
https://ncbi.nlm.nih.gov/pubmed/19911776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902012m
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