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Silver-Mediated Allylic Disulfide Rearrangement for Conjugation of Thiols in Protic Media

[Image: see text] Alkyl and aryl allyl disulfides are induced to undergo the desulfurative allylic rearrangement by silver nitrate in protic solvents at room temperature, thereby removing the necessity for the use of phosphines as thiophilic reagents. The silver-mediated reaction functions at ambien...

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Detalhes bibliográficos
Main Authors: Crich, David, Subramanian, Venkataraman, Karatholuvhu, Maheswaran
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2852026/
https://ncbi.nlm.nih.gov/pubmed/19911776
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo902012m
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