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Protecting Group-Free Glycoligation by the Desulfurative Rearrangement of Allylic Disulfides as a Means of Assembly of Oligosaccharide Mimetics
[Image: see text] 2-(2-Pyridyldithio-3-butenyl) glycosides react with carbohydrate-based thiols in a two step process involving sulfenyl transfer followed by desulfurative 2,3-allylic rearrangement, promoted by either triphenylphosphine or silver nitrate, to give novel saccharide mimetics. In an alt...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3094498/ https://ncbi.nlm.nih.gov/pubmed/21428425 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo102411j |
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