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A cysteine selenosulfide redox switch for protein chemical synthesis

The control of cysteine reactivity is of paramount importance for the synthesis of proteins using the native chemical ligation (NCL) reaction. We report that this goal can be achieved in a traceless manner during ligation by appending a simple N-selenoethyl group to cysteine. While in synthetic orga...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Diemer, Vincent, Ollivier, Nathalie, Leclercq, Bérénice, Drobecq, Hervé, Vicogne, Jérôme, Agouridas, Vangelis, Melnyk, Oleg
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7244499/
https://ncbi.nlm.nih.gov/pubmed/32444769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-16359-6
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