Polyethylene with Reverse Co-monomer Incorporation: From an Industrial Serendipitous Discovery to Fundamental Understanding

A triethylaluminium(TEAl)-modified Phillips ethylene polymerisation Cr/Ti/SiO(2) catalyst has been developed with two distinct active regions positioned respectively in the inner core and outer shell of the catalyst particle. DRIFTS, EPR, UV-Vis-NIR DRS, STXM, SEM-EDX and GPC-IR studies revealed tha...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Cicmil, Dimitrije, Meeuwissen, Jurjen, Vantomme, Aurélien, Wang, Jian, van Ravenhorst, Ilse K, van der Bij, Hendrik E, Muñoz-Murillo, Ara, Weckhuysen, Bert M
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2015
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4643190/
https://ncbi.nlm.nih.gov/pubmed/26349452
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201506718
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