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Real‐time Analysis of a Working Triethylaluminium‐Modified Cr/Ti/SiO(2) Ethylene Polymerization Catalyst with In Situ Infrared Spectroscopy

A diffuse reflectance infrared Fourier‐transform (DRIFT) study has been conducted at 373 K and 1 bar on an industrial Cr/Ti/SiO(2) Phillips‐type catalyst modified with, and without, triethylaluminium (TEAl) as co‐catalyst. The reaction rate of the polymerization of ethylene, as monitored by the incr...

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Bibliografiske detaljer
Udgivet i:ChemCatChem
Main Authors: Cicmil, Dimitrije, Meeuwissen, Jurjen, Vantomme, Aurélien, Weckhuysen, Bert M.
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2016
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5084731/
https://ncbi.nlm.nih.gov/pubmed/27840661
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201600200
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