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Accessing Ni(III)-Thiolate Versus Ni(II)-Thiyl Bonding in a Family of Ni–N(2)S(2) Synthetic Models of NiSOD

[Image: see text] Superoxide dismutase (SOD) catalyzes the disproportionation of superoxide (O(2)(• −)) into H(2)O(2) and O(2)(g) by toggling through different oxidation states of a first-row transition metal ion at its active site. Ni-containing SODs (NiSODs) are a distinct class of this family of...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Broering, Ellen P., Dillon, Stephanie, Gale, Eric M., Steiner, Ramsey A., Telser, Joshua, Brunold, Thomas C., Harrop, Todd C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4630978/
https://ncbi.nlm.nih.gov/pubmed/25835183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic503124f
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