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Dialkyl Ether Formation via Nickel-Catalyzed Cross Coupling of Acetals and Aryl Iodides()
A new substrate class for Ni-catalyzed C(sp(3)) cross-coupling reactions is reported. We show that α-oxy radicals generated from abundant and stable benzylic acetals, TMSCl, and a mild reductant can participate in chemoselective cross coupling with aryl iodides and a vinyl triflate using a 2,6-bis(N...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2015
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4629785/ https://ncbi.nlm.nih.gov/pubmed/26219537 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201503936 |
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