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Catalytic Enantioselective Peroxidation of α, β-Unsaturated Aldehydes for the Asymmetric Synthesis of Biologically Important Chiral Endoperoxides

We have developed an unprecedented highly enantioselective catalytic peroxidation of enals. Critical to this development is the discovery that varying the structure of the hydroperoxides has a significant impact on the enantioselectivity of the organocatalytic asymmetric peroxidation. This novel tra...

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Bibliografiske detaljer
Udgivet i:J Am Chem Soc
Main Authors: Hu, Lin, Lu, Xiaojie, Deng, Li
Format: Artigo
Sprog:Inglês
Udgivet: 2015
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4620706/
https://ncbi.nlm.nih.gov/pubmed/26101971
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05345
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