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Catalytic Enantioselective Peroxidation of α, β-Unsaturated Aldehydes for the Asymmetric Synthesis of Biologically Important Chiral Endoperoxides
We have developed an unprecedented highly enantioselective catalytic peroxidation of enals. Critical to this development is the discovery that varying the structure of the hydroperoxides has a significant impact on the enantioselectivity of the organocatalytic asymmetric peroxidation. This novel tra...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4620706/ https://ncbi.nlm.nih.gov/pubmed/26101971 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05345 |
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