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Divergent Reactivity of Rhodium (I) Carbenes Derived from Indole Annulation()
Rh(I)-carbenes were generated from propargylic alcohol derivatives as the result of a dehydrative indole annulation. Depending on the choice of the electron-withdrawing group on the aniline nitrogen nucleophile, either cyclopropanation product or dimerization product was obtained chemoselectively. I...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2015
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4612373/ https://ncbi.nlm.nih.gov/pubmed/26480329 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505329 |
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