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Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4 + 2] cycloaddition of vinylallene and unactivated alkyne

A Rh-catalyzed 1,3-acyloxy migration of propargyl ester followed by intramolecular [4 + 2] cycloaddition of vinylallene and unactivated alkyne was developed. This tandem reaction provides access to bicyclic compounds containing a highly functionalized isotoluene or cyclohexenone structural motif, wh...

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Detalhes bibliográficos
Main Authors: Huang, Suyu, Li, Xiaoxun, Lin, Claire L., Guzei, Ilia A., Tang, Weiping
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3334501/
https://ncbi.nlm.nih.gov/pubmed/22252254
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2cc17406e
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