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Ligand-Enabled Meta-C–H Alkylation and Arylation Using A Modified Norbornene
2-Carbomethoxynorbornene is identified as a more effective transient mediator to promote a Pd(II)-catalyzed meta-C(sp(2))–H alkylation of amides with various alkyl iodides as well as arylation with previously incompatible aryl iodides. The use of a tailor-made quinoline ligand is also crucial for th...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4573956/ https://ncbi.nlm.nih.gov/pubmed/26313012 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b08914 |
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