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Ligand-Enabled Meta-Selective C–H Arylation of Nosyl Protected Phenethylamines, Benzylamines and 2-Aryl Anilines

A Pd-catalyzed, meta-selective C−H arylation of nosyl-protected phenethylamines, and benzylamines is disclosed using a combination of norbornene and pyridine-based ligands. Subjecting 2-aryl anilines to this protocol lead to meta-C–H arylation at the remote aryl ring. A diverse range of aryl iodides...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Ding, Qiuping, Ye, Shengqing, Cheng, Guolin, Wang, Peng, Farmer, Marcus E., Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5497681/
https://ncbi.nlm.nih.gov/pubmed/27951637
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11097
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