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Probing Cu(I) in Homogeneous Catalysis using High-Energy-Resolution Fluorescence-Detected X-ray Absorption Spectroscopy

Metal-to-ligand charge transfer excitations in Cu(I) X-ray absorption spectra are introduced as spectroscopic handles for the characterization of species in homogeneous catalytic reaction mixtures. Analysis is supported by correlation of a spectral library to calculations and to complementary spectr...

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Publicat a:Chem Commun (Camb)
Autors principals: Walroth, Richard C., Uebler, Jacob W. H., Lancaster, Kyle M.
Format: Artigo
Idioma:Inglês
Publicat: 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC4540364/
https://ncbi.nlm.nih.gov/pubmed/25994112
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5cc01827g
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