Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L(3)-edge X-ray absorption spectroscopy

The addition of various oxidants to the near-linear Sm(ii) complex [Sm(N(††))(2)] (1), where N(††) is the bulky bis(triisopropylsilyl)amide ligand {N(Si(i)Pr(3))(2)}, afforded a family of heteroleptic three-coordinate Sm(iii) halide complexes, [Sm(N(††))(2)(X)] (X = F, 2-F; Cl, 2-Cl; Br, 2-Br; I, 2-...

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Detalhes bibliográficos
Publicado no:Dalton Trans
Main Authors: Goodwin, Conrad A. P., Réant, Benjamin L. L., Kragskow, Jon G. C., DiMucci, Ida M., Lancaster, Kyle M., Mills, David P., Sproules, Stephen
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6083822/
https://ncbi.nlm.nih.gov/pubmed/29790545
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt01452c
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