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Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L(3)-edge X-ray absorption spectroscopy
The addition of various oxidants to the near-linear Sm(ii) complex [Sm(N(††))(2)] (1), where N(††) is the bulky bis(triisopropylsilyl)amide ligand {N(Si(i)Pr(3))(2)}, afforded a family of heteroleptic three-coordinate Sm(iii) halide complexes, [Sm(N(††))(2)(X)] (X = F, 2-F; Cl, 2-Cl; Br, 2-Br; I, 2-...
Tallennettuna:
| Julkaisussa: | Dalton Trans |
|---|---|
| Päätekijät: | , , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
Royal Society of Chemistry
2018
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6083822/ https://ncbi.nlm.nih.gov/pubmed/29790545 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt01452c |
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