Heteroleptic samarium(iii) halide complexes probed by fluorescence-detected L(3)-edge X-ray absorption spectroscopy

The addition of various oxidants to the near-linear Sm(ii) complex [Sm(N(††))(2)] (1), where N(††) is the bulky bis(triisopropylsilyl)amide ligand {N(Si(i)Pr(3))(2)}, afforded a family of heteroleptic three-coordinate Sm(iii) halide complexes, [Sm(N(††))(2)(X)] (X = F, 2-F; Cl, 2-Cl; Br, 2-Br; I, 2-...

Full description

Saved in:
Bibliographic Details
Published in:Dalton Trans
Main Authors: Goodwin, Conrad A. P., Réant, Benjamin L. L., Kragskow, Jon G. C., DiMucci, Ida M., Lancaster, Kyle M., Mills, David P., Sproules, Stephen
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2018
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC6083822/
https://ncbi.nlm.nih.gov/pubmed/29790545
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8dt01452c
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items