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Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations

In this full article, detailed development of a catalytic decarbonylation of conjugated monoynones to synthesize disubstituted alkynes is described. The reaction scope and limitation has been thoroughly investigated, and a broad range of functional groups including heterocycles were compatible under...

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שמור ב:
מידע ביבליוגרפי
הוצא לאור ב:Chem Sci
Main Authors: Dermenci, Alpay, Whittaker, Rachel E., Gao, Yang, Cruz, Faben A., Yu, Zhi-Xiang, Dong, Guangbin
פורמט: Artigo
שפה:Inglês
יצא לאור: Royal Society of Chemistry 2015
נושאים:
גישה מקוונת:https://ncbi.nlm.nih.gov/pmc/articles/PMC4517480/
https://ncbi.nlm.nih.gov/pubmed/26229587
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00584a
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