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Enzymatic Enantioselective Decarboxylative Protonation of Heteroaryl Malonates
The enzyme aryl/alkenyl malonate decarboxylase (AMDase) catalyses the enantioselective decarboxylative protonation (EDP) of a range of disubstituted malonic acids to give homochiral carboxylic acids that are valuable synthetic intermediates. AMDase exhibits a number of advantages over the non-enzyma...
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| Udgivet i: | Chemistry |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
WILEY-VCH Verlag
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4517146/ https://ncbi.nlm.nih.gov/pubmed/25766433 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201406014 |
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