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Enzymatic Catalysis of Proton Transfer and Decarboxylation Reactions

Deprotonation of carbon and decarboxylation at enzyme active sites proceed through the same carbanion intermediates as for the uncatalyzed reactions in water. The mechanism for the enzymatic reactions can be studied at the same level of detail as for nonenzymatic reactions, using the mechanistic too...

Ausführliche Beschreibung

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Bibliographische Detailangaben
1. Verfasser: Richard, John P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2011
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3596839/
https://ncbi.nlm.nih.gov/pubmed/23505326
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1351/PAC-CON-11-02-05
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