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Enzymatic Catalysis of Proton Transfer and Decarboxylation Reactions
Deprotonation of carbon and decarboxylation at enzyme active sites proceed through the same carbanion intermediates as for the uncatalyzed reactions in water. The mechanism for the enzymatic reactions can be studied at the same level of detail as for nonenzymatic reactions, using the mechanistic too...
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| Formato: | Artigo |
| Idioma: | Inglês |
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2011
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| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3596839/ https://ncbi.nlm.nih.gov/pubmed/23505326 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1351/PAC-CON-11-02-05 |
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