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Formation and Properties of a Bicyclic Silylated Digermene
In the presence of PMe(3) or N-heterocyclic carbenes, the reaction of oligosilanylene dianions with GeCl(2)⋅dioxane gives germylene–base adducts. After base abstraction, the free germylenes can dimerize by formation of a digermene. An electrochemical and theoretical study of a bicyclic tetrasilylate...
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| Publicado no: | Chemistry |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
WILEY-VCH Verlag
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4506559/ https://ncbi.nlm.nih.gov/pubmed/24981992 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201402785 |
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