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Mild Silver-Mediated Geminal Difluorination of Styrenes Using an Air- and Moisture-Stable Fluoroiodane Reagent**

An air- and moisture-stable fluoroiodane in the presence of AgBF(4) is suitable for selective geminal difluorination of styrenes under mild reaction conditions. One of the C=F bonds is formed by transfer of electrophilic fluorine from the hypervalent iodine reagent, while the other one arises from t...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Ilchenko, Nadia O, Tasch, Boris O A, Szabó, Kálmán J
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY-VCH Verlag 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4501311/
https://ncbi.nlm.nih.gov/pubmed/25335468
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201408812
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