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Mild Silver-Mediated Geminal Difluorination of Styrenes Using an Air- and Moisture-Stable Fluoroiodane Reagent**
An air- and moisture-stable fluoroiodane in the presence of AgBF(4) is suitable for selective geminal difluorination of styrenes under mild reaction conditions. One of the C=F bonds is formed by transfer of electrophilic fluorine from the hypervalent iodine reagent, while the other one arises from t...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
WILEY-VCH Verlag
2014
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4501311/ https://ncbi.nlm.nih.gov/pubmed/25335468 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201408812 |
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