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Asymmetric hydrosilylation of ketones catalyzed by complexes formed from trans-diaminocyclohexane-based diamines and diethylzinc

ABSTRACT: Chiral acyclic and macrocyclic amines derived from trans-1,2-diaminocyclohexane in complexes with diethylzinc efficiently catalyze asymmetric hydrosilylation of aryl–alkyl and aryl–aryl ketones with enantiomeric excess of the product up to 86 %. A trianglamine ligand with a cyclic structur...

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Foilsithe in:Monatsh Chem
Main Authors: Gajewy, Jadwiga, Gawronski, Jacek, Kwit, Marcin
Formáid: Artigo
Teanga:Inglês
Foilsithe: Springer Vienna 2012
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4494764/
https://ncbi.nlm.nih.gov/pubmed/26166868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00706-012-0754-0
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