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Synthesis of β-C-galactosyl d- and l-alanines†

Synthesis of β-C-d-galactosyl d- and l-alanines is carried out via a highly stereoselective Grignard reaction of glycosyl iodides, Sharpless dihydroxylation and S(N)2 displacement of the corresponding mesylate or tosylate. Alternatively, attempted triflation of the intermediate alcohols triggers a s...

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Détails bibliographiques
Publié dans:Org Biomol Chem
Auteurs principaux: Thota, V. Narasimharao, Gervay-Hague, Jacquelyn, Kulkarni, Suvarn S.
Format: Artigo
Langue:Inglês
Publié: 2012
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4492545/
https://ncbi.nlm.nih.gov/pubmed/22961309
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2ob26078f
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