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Chemoenzymatic Synthesis of Cholesteryl-6-O-tetradecanoyl-α-D-glucopyranoside: A Product of Host Cholesterol Efflux Promoted by Helicobacter pylori

In a three-step protocol involving regioselective enzymatic acylation, per-O-trimethylsilylation, and a one-pot α-glycosidation/deprotection sequence, cholesteryl 6-O-tetradecanoyl-α-D-glucopyranoside (α-CAG) of Helicobacter pylori is afforded starting from glucose in an overall yield of 45%. The pr...

詳細記述

保存先:
書誌詳細
出版年:Chem Commun (Camb)
主要な著者: Davis, Ryan A., Lin, Chun-Hung, Gervay-Hague, Jacquelyn
フォーマット: Artigo
言語:Inglês
出版事項: 2012
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC4271795/
https://ncbi.nlm.nih.gov/pubmed/22854787
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2cc33948j
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