Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol

Copper-exchanged zeolites with mordenite structure mimic the nuclearity and reactivity of active sites in particulate methane monooxygenase, which are enzymes able to selectively oxidize methane to methanol. Here we show that the mordenite micropores provide a perfect confined environment for the hi...

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Publicado no:Nat Commun
Main Authors: Grundner, Sebastian, Markovits, Monica A.C., Li, Guanna, Tromp, Moniek, Pidko, Evgeny A., Hensen, Emiel J.M., Jentys, Andreas, Sanchez-Sanchez, Maricruz, Lercher, Johannes A.
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Pub. Group 2015
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4491810/
https://ncbi.nlm.nih.gov/pubmed/26109507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8546
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