Single-site trinuclear copper oxygen clusters in mordenite for selective conversion of methane to methanol

Copper-exchanged zeolites with mordenite structure mimic the nuclearity and reactivity of active sites in particulate methane monooxygenase, which are enzymes able to selectively oxidize methane to methanol. Here we show that the mordenite micropores provide a perfect confined environment for the hi...

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Pubblicato in:Nat Commun
Autori principali: Grundner, Sebastian, Markovits, Monica A.C., Li, Guanna, Tromp, Moniek, Pidko, Evgeny A., Hensen, Emiel J.M., Jentys, Andreas, Sanchez-Sanchez, Maricruz, Lercher, Johannes A.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Nature Pub. Group 2015
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4491810/
https://ncbi.nlm.nih.gov/pubmed/26109507
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8546
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