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Iron(II)-Catalyzed Asymmetric Epoxidation of Trisubstituted α,β-Unsaturated Esters
An asymmetric epoxidation of trisubstituted α,β-unsaturated esters is described. The oxidation utilizes a pseudo-C(2)-symmetric iron(II) catalyst [Fe(L*)(2)(CH(3)CN)(OTf)](OTf) and peracetic acid as oxidant, yielding the α,β-epoxyesters in high enantiomeric purity (up to 99% ee).
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| Udgivet i: | European J Org Chem |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2014
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4486291/ https://ncbi.nlm.nih.gov/pubmed/26146482 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.201403220 |
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